The two angles are a linear pair.
(Explanations down below!)
Linear pair angles must add up to 180 degrees. You can tell that the two angles add up to 180 degrees because they form a straight line (which is 180 degrees).
Complementary angles add up to 90 degrees. The two angles are not complementary because they do not form a 90 degree angle (right triangle, square in corner, like a L shape).
Vertical angles are opposite each other and are equal to one another. These angles are adjacent to each other and do not look similar.
